Ok I am a bit behind my schedule but I have the following to report.
When set to rear curtain sync the pop up flash does not emit any visible flash at all when the shutter opens and only fires when it closes
With a speedlight in the hot shoe the flash fires at opening and closing.
I have tried an experiment as follows.
Taken a photo at normal settings with the flash firing at opening only
Taken the same photo again with rear curtain sync and the flash fires twice and looks identical to the first photo
Taken the photo again with the same bulb settings and covering the speedlight before the shutter closes. This picture is not as light as the pictures in the previous two shots.
It seems to me that the pop up flash works correctly as with rear curtain surely you don't want any flash at all when the shutter opens only when it closes
Edward